Citric Acid Anhydrous

    • Product Name: Citric Acid Anhydrous
    • Chemical Name (IUPAC): 2-hydroxypropane-1,2,3-tricarboxylic acid
    • CAS No.: 77-92-9
    • Chemical Formula: C6H8O7
    • Form/Physical State: White crystalline powder
    • Factroy Site: Lingwu, Yinchuan, Ningxia, China
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Anhui Liwei Chemical Co.,Limited
    • CONTACT NOW
    Specifications

    HS Code

    570579

    Cas Number 77-92-9
    Molecular Formula C6H8O7
    Molecular Weight 192.12 g/mol
    Appearance White crystalline powder
    Odor Odorless
    Solubility In Water 146 g/100 mL (20°C)
    Melting Point 153°C
    Ph Of 1 Solution Approximately 2.2
    Boiling Point Decomposes before boiling
    Density 1.66 g/cm³
    E Number E330
    Synonyms 2-Hydroxy-1,2,3-propanetricarboxylic acid
    Storage Temperature Store at room temperature
    Stability Stable under recommended storage conditions
    Hazard Statements May cause eye irritation

    As an accredited Citric Acid Anhydrous factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Citric Acid Anhydrous is packaged in a 25 kg white plastic-lined kraft paper bag, labeled with product name, batch number, and safety information.
    Container Loading (20′ FCL) 20′ FCL loads 25 metric tons of Citric Acid Anhydrous, packed in 25kg kraft bags, 1,000 bags per container, palletized/unpalletized.
    Shipping Citric Acid Anhydrous is shipped in tightly sealed, moisture-resistant containers such as fiber drums, polyethylene bags, or kraft paper sacks. Store and transport in a cool, dry, well-ventilated area away from incompatible substances. Handle carefully to prevent damage or spills. Ensure compliance with local and international shipping regulations.
    Storage Citric Acid Anhydrous should be stored in a tightly closed container, in a cool, dry, well-ventilated area away from moisture and incompatible substances such as strong oxidizing agents. Keep away from direct sunlight and heat sources. The storage area should be free from combustible materials, and proper labeling should be ensured to prevent accidental misuse. Handle with suitable personal protective equipment.
    Shelf Life Citric Acid Anhydrous typically has a shelf life of 3 years when stored in a cool, dry, tightly sealed container away from moisture.
    Application of Citric Acid Anhydrous

    Applications of Citric Acid Anhydrous in Industrial Manufacturing

    As a direct producer of citric acid anhydrous, we enable consistent quality and traceability for industrial customers across critical downstream sectors. Below we highlight real-world manufacturing scenarios where our citric acid meets industry-specific technical and compliance requirements throughout the value chain.

    1. Food and Beverage Acidulant

    Food and beverage processors depend on citric acid as an acidulant, flavor enhancer, and pH adjuster in a range of formulations—especially where precise acidity, shelf stability, and national food safety mandates are essential. Our production facilities supply FSSC 22000 and ISO 22000 certified material, controlled through HACCP and GMP protocols, to beverage, confectionery, and processed food manufacturers globally.

    Industry compliance standards

    • GB 1886.235 (China National Food Safety Standard for Citric Acid)
    • FCC (Food Chemicals Codex) Monograph
    • 21 CFR 184.1033 (U.S. FDA Direct Food Substances Affirmed as Generally Recognized As Safe—GRAS)
    • EU Regulation (EC) No 1333/2008 on food additives (E330)

    Typical usage ratio

    • 0.03–0.3% (w/w) in beverages, varying with product acidity requirements
    • 0.05–0.5% in sugar confectionery for flavor balance and gelation control
    • Dosage adjusted based on total titratable acidity and target pH

    Downstream process integration

    • Dosed during syrup blending step in soft drinks and juices
    • Incorporated at melt or mixing stage for confectionery and jams
    • Used as a buffering and chelating agent for canned fruits and vegetables

    Final product types

    • Carbonated and still beverages (juices, sodas, sports drinks)
    • Hard and soft candies, gummies, fruit preserves
    • Ready-to-eat sauces, jams, fruit-based snack items

    2. Pharmaceutical Excipient and Active Ingredient

    Pharmaceutical groups formulate our citric acid into granular, tableting, and liquid preparations where tight control of purity, identity, and residual impurities is required. Its main uses include adjusting and stabilizing pH in oral syrups, as an effervescent base with bicarbonates, and as a chelating agent for active ingredient solubility. All batches undergo stringent API and excipient quality controls according to international pharmacopoeia requirements.

    Industry compliance standards

    • Ph. Eur. (European Pharmacopoeia) Monograph 01/2017:0419
    • USP-NF (United States Pharmacopeia–National Formulary) Monograph
    • ChP (Chinese Pharmacopoeia) 2020 Edition
    • cGMP compliance per ICH Q7 guidelines

    Typical usage ratio

    • 5–15% in solid effervescent tablets and powders
    • 0.1–0.5% as pH modifier in oral syrups and suspensions
    • Usage dependent on dosage form, target dissolution profile, and stability testing

    Downstream process integration

    • Introduced during wet granulation for tablet manufacturing
    • Directly blended with active substances and excipients in effervescent systems
    • Added to aqueous phase for liquid or semi-solid forms

    Final product types

    • Effervescent tablets and powders (paracetamol, vitamin C, multivitamin blends)
    • Oral syrups (antibiotics, antihistamines, pediatric supplements)
    • Liquid suspensions and injectable preparations (upon regulatory approvals)

    3. Household and Industrial Cleaning Formulations

    In cleaning and detergency, citric acid serves as a primary chelant, scale remover, and pH regulator to boost the efficacy of surfactants and control water hardness, particularly in concentrated liquid, powder, and gel formulations. Detergent brands and commercial cleaning suppliers specify raw materials compliant with REACH and EPA Safer Choice standards to minimize environmental and user risks.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006
    • EPA Safer Chemical Ingredients List (U.S.)
    • Detergents Regulation (EC) No 648/2004
    • AISE Charter for Sustainable Cleaning

    Typical usage ratio

    • 1–8% in household dishwashing tablets and machine detergents
    • 10–25% in limescale removers, bathroom descalers, and surface cleaning gels
    • Formulation ratio shifts with water hardness and intended cleaning application

    Downstream process integration

    • Dry blending for powdered products
    • Solution phase dosing for gels and liquid formulas at pre-mix or final tank
    • Compounding with surfactants, builders, and colorants before final packaging

    Final product types

    • Machine dishwashing detergents and tablets
    • Descaling agents for kitchen and bathroom use
    • Multi-surface and hard surface cleaners for institutional use

    4. Industrial Metal Surface Treatment and Cleaning

    Circuit board assemblers, metal finishing shops, and scale removal specialists use our citric acid for passivation, rust removal, and chelating operations. Its controlled impurity profile—free from ferrous and other catalytically active metals—enables consistent performance as a safer alternative to nitric acid while maintaining compliance with industrial cleaning regulations and ensuring minimal residue.

    Industry compliance standards

    • ASTM A967/A967M (Standard Specification for Chemical Passivation Treatments for Stainless Steel Parts)
    • SAE AMS 2700 (Passivation of Corrosion Resistant Steels—Citric Acid Method)
    • REACH Regulation (EC) No 1907/2006 for raw material handling
    • Local employee safety standards (e.g., OSHA 1910.1200 for hazardous chemicals)

    Typical usage ratio

    • 4–10% (w/w) in passivation baths, based on stainless steel type and required exposure time
    • 10–20% for rust and scale removal in soak tanks and circulating systems
    • Concentration tailored to the degree of oxidation and batch process parameters

    Downstream process integration

    • Charged into pre-heated aqueous baths for immersion or spray applications
    • Applied during the post-pickling rinse or final surface conditioning stage
    • Blended with corrosion inhibitors or anti-foam agents as needed

    Final product types

    • Stainless steel pipes, valves, medical devices
    • Electronic components, printed circuit boards after flux removal and passivation
    • Industrial equipment with high corrosion resistance requirements

    5. Cosmetics and Personal Care Manufacturing

    Regulated personal care and cosmetics manufacturers use citric acid for pH buffering, chelation, and aqueous phase stabilization in creams, shampoos, and rinse-off products. Producers must meet region-specific cosmetic regulations while achieving high transparency and microbiological stability in end products. Trace metal and contamination analysis forms part of every outgoing lot for these applications.

    Industry compliance standards

    • EU Regulation (EC) No 1223/2009 on Cosmetic Products
    • U.S. FDA Title 21 CFR 700–799 for Over-the-Counter Cosmetics
    • China Cosmetic Supervision and Administration Regulation (CSAR)
    • ISO 22716 (Cosmetic GMP)

    Typical usage ratio

    • 0.05–0.5% in skin creams, lotions, and hair conditioners as a pH adjuster
    • Up to 1% in color-care shampoos and bath products
    • Ratio depends on target pH (usually 4.0–6.5) and ingredient compatibility

    Downstream process integration

    • Dosed into water phase during primary emulsion preparation or surfactant blend step
    • Neutralized with alkaline agents in final pH adjustment before filling
    • Quality controlled for clarity, odor, and trace heavy metals

    Final product types

    • Facial creams, moisturizing lotions
    • Cleansing gels, micellar waters, skin toners
    • Shampoos, hair conditioners, leave-in treatments

    6. Water Treatment and Boiler Descaling

    Industrial water treatment facilities and boiler maintenance contractors incorporate citric acid for closed-loop cleaning and descaling tasks due to its effectiveness in dissolving mineral deposits and controlling citrate complexes during system reactivation. Its selection is based on low toxicity and compatibility with a wide range of system materials, subject to national wastewater discharge norms and chemical handling protocols.

    Industry compliance standards

    • EN 12124 (Chemicals used for treatment of water intended for human consumption—Citric acid)
    • U.S. EPA Safe Drinking Water Act (SDWA) guidelines
    • Local environmental discharge permits and handling protocols
    • Operational safety standards for hazardous materials (OSHA, EU CLP Regulation)

    Typical usage ratio

    • 1–10% in closed-loop descaling and flush cycles for heat exchangers and evaporators
    • 15–20% for intensive boiler descale prior to system commissioning or major maintenance
    • Dosage determined by assessment of scale thickness, flow rate, and metal substrate

    Downstream process integration

    • Prepared as concentrated cleaning solution for recirculating descaling cycles
    • Injected into system with flow monitoring and automated pH endpoint control
    • Rinsed thoroughly before system restart and performance validation

    Final product types

    • Cleaned industrial boilers and heat exchangers
    • Descaled piping systems and condensate return lines
    • Potable water system components with post-treatment certificates

    Free Quote

    Competitive Citric Acid Anhydrous prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8615380400285 or mail to sales2@liwei-chem.com.

    We will respond to you as soon as possible.

    Tel: +8615380400285

    Email: sales2@liwei-chem.com

    Get Free Quote of Anhui Liwei Chemical Co.,Limited

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    Citric Acid Anhydrous: The Backbone of Clean, Flavor, and Formulation

    Our Experience with Citric Acid Anhydrous Production

    After years overseeing the fermentation vats, filtration lines, and refining columns of citric acid facilities, certain truths become clear. Citric acid anhydrous production isn’t about a quick run through a chemical process. It calls for precise temperature control, steady pH balance, and high-efficiency filtering. Using non-GMO corn substrates and rigorously controlling the presence of trace minerals, we consistently reach the high purity standard demanded across global markets. Decades have shown that attention to these basic steps—frequent sampling, clean equipment, careful drying—makes the difference between reliable product and inconsistent batches.

    In our drying rooms, moisture levels get monitored every shift. Here, people really notice the anhydrous character—no moisture sticking to the grains, no clumping, free-flowing fine crystals. It sounds simple, but reaching water content below 0.5% by weight calls for strict discipline. That’s why we never take shortcuts with the drying cycle or packaging environment, since trace moisture means harder handling for our customers and potentially spoiled performance in finished goods.

    Models and Specifications: Focusing on What Works

    The specification people ask about most is the granule size. We produce both fine powder and a slightly coarser crystal grade. Our anhydrous powder passes a 20-mesh sieve easily, while our crystal form fits well in operations that value a bit less dust and more blend consistency. In nearly every batch, the assay runs between 99.5% and 100.5% citric acid, based on dry basis calculations. We see buyers from the food, beverage, and pharmaceutical industries consistently choose both grades, depending on application needs.

    Impurities matter. We’ve spent years reducing heavy metal content and residual sulfates. Our offers almost always guarantee heavy metal residues below 5 ppm and sulfate below 150 ppm, since regulatory bodies from the US, EU, and Asia all keep tight limits on these. Bulk density targets strike a balance between flowability and packing efficiency, which helps streamline shipping and storage. Routinely, our anhydrous grade has a bulk density between 800–900 kg/m³.

    Usage: Where It Delivers Results

    Citric acid anhydrous does more than “acidulate” and “preserve.” Bakers see it as a fast-acting leavening partner with sodium bicarbonate—no off-flavor, no aftertaste, and it leaves bread lighter and more shelf-stable. Beverage formulators rely on pure batches for clear, bright taste in sodas and juices. Vitamin C tablets reach their expected tartness and solubility with fine powder anhydrous that disperses instantly. Pharmaceutical makers regularly send us requests for lowest-possible moisture levels—tablets can harden or react prematurely with higher moisture. This is why we insist on regular Karl Fischer titrations, batch by batch.

    Dairy and cheese plants appreciate nimble pH correction in milk streams. Candy makers tell us the lack of moisture helps create smooth, non-sticky textures in finished product, from hard candy drops to pectin jellies, where undesired crystallization must be kept in check. Over time, personal care formulators switched from monohydrate to anhydrous grades for bath bombs and effervescent powders because of improved shelf-life and more consistent fizzing action. It helps create transparent shampoos and cleaning solutions without residue. In industrial water treatment, it chelates metal ions, reducing scaling and stabilizing formulations that must remain effective over long storage.

    How Anhydrous Differs: Beyond the Obvious

    People often compare anhydrous citric acid to its monohydrate relative. Both share molecular weight, acid strength, and chelating power, but field experience shows they behave differently under real conditions. Anhydrous leans into applications requiring long shelf-life, higher flowability, and controlled reactivity. Monohydrate picks up atmospheric moisture easily and can cake in storage, so food and pharma teams prefer anhydrous for high-speed mixing or environments where humidity control isn’t perfect. We learned years ago that manufacturing anhydrous requires tighter control at every step—right from fermenter sterility through final drying and packaging. Skipping the last bits of moisture makes shipping cleaner, extends usable life, and reduces the chance for spoilage or clumping, especially in humid climates.

    Pharmaceutical quality standards such as USP and EP list very tight limits on microbial content and elemental impurities—especially in the anhydrous form. For certain injectable or tableted medicines, monohydrate’s water content actually interferes with formulation or final product consistency. This feedback—straight from tablet press operators or QA labs—motivates us to run sterile packaging lines for our pharma-grade anhydrous product. The investment in stainless steel tanks, sealed negative pressure environments, and weekly audits means our product consistently clears these hurdles.

    Some customers focus on the environmental side—anhydrous citric acid’s lower water content means smaller freight weights and fewer transportation energy demands. It stores longer without special temperature control. Food processors often pay a premium for this stability, especially when product moves across continents or sits in high-bay warehouses for months. Plant operators know from experience that switching from monohydrate to anhydrous saves downtime spent breaking up caked material.

    Quality, Traceability, and Trust Over Shortcuts

    Ownership of the production process from raw corn delivery to finished drum offers clear advantages. Only daily batch logs and frequent operator training have allowed us to hit tight assay targets and keep off-spec batches out of customer lines. In the early years, occasional contamination or variable drying times would spike customer complaints—since then, we’ve invested in automated sensors, rigorous sampling, and transparent record keeping. It means everyone, from plant engineers to shipping clerks, sees the same batch numbers and test results.

    Traceability supports big goals—think infant formula makers or parenteral nutrition suppliers, both of whom require not just purity but detailed proof of origin and test results. For these, our full lot tracking provides interlocking records: raw material source, process parameters, analyst IDs, and final batch data, signed and archived. Over time, these practices have hauled us through multiple third-party audits, allowing our product to support demanding global markets. If raw material issues crop up—say, an upstream non-GMO corn shipment gives abnormal glucose readings—batch segregation and root cause analysis prevent compromised product entering sensitive applications.

    Our experience says regulatory shifts rarely impact quality if fundamentals stay consistent. We’ve seen new heavy metals protocols and region-specific tests arrive, but plant discipline wins every time. This includes regular staff training, vendor qualification on non-GMO feedstock, and prompt upgrades to analytical instruments. Internal audits—much more time-consuming than external checks—highlight small leaks or temperature excursions before defects reach finished product bins or shipping containers.

    Meeting Market Shifts and Technical Demands

    Demand patterns keep changing. Today’s beverage brands want cleaner taste and reliable mouthfeel, moving to acidulants with traceable origins and consistent grading. Shipping blenders and co-packers want documented control on mesh size, no off-flavors, and fast dissolution. Our investment in larger fluid bed driers and rejected-batch traceability allows for fine-tuned delivery, not just mass commodity production.

    Pharmaceutical customers increasingly require extra compliance claims: allergen-free, kosher, halal, and non-GMO certifications. Instead of treating these as afterthoughts, we have woven such protocols into the mainline process, right from raw corn handling through endotoxin testing and packing. Our lab team has been trained against both local and global monographs and works directly with auditors from customer companies before each major new launch. With new demands for elemental impurity compliance, we recently added ICP-MS technology to supplement our classic wet analyses for cadmium, arsenic, and lead.

    As personal care and cleaning segments grow, the need to deliver ultra-low residues—especially for skin-contact and rinse-off products—demands regular revalidation of our processes. Our citric acid anhydrous, in particular, finds favor because its lack of moisture enables better control over stability and shelf life in these sensitive blends. Feedback leads to improvement, so we open our factory to direct audit and cross-check with customer R&D teams.

    Real-World Product Reliability: Lessons from the Plant

    Long-term business starts with reliability. Whether in food acidulation, tablet pressing, or specialty detergent blending, each user faces the same worry—will the next shipment perform just like the last? We’ve seen firsthand how a surprise in one batch can cause an entire day’s production to halt—dairy tanks diverted, pharma lines reset, or packaging waste spikes. This makes us extra cautious in chasing up every deviation, whether it’s a slow filter rate, a spike in metal content, or unnoticed clumping upon delivery.

    Our engineers frequently work alongside R&D teams, discovering new process steps or better mixing techniques that fit citric acid anhydrous’s properties. Whether supporting beverage fortification or personal care effervescence, we offer samples and run pilot blends, gathering firsthand data on solubility, flow rates, and downstream blending behaviors. This technical closeness removes guesswork and smooths process transitions during scale-up.

    Waste disposal and environmental duty also shape our production choices. We continually invest in cleaner fermentation inputs and energy-efficient driers to lessen the environmental footprint, in line with increasing customer focus on sustainability metrics. Where possible, side streams—spent fermentation broth, used filtration aids—are recycled into animal feed or soil improvement, instead of simple disposal. These steps come from operational necessity and responsibility, not empty promises.

    Addressing Real Issues: Price, Supply, and Risk

    Across recent years, supply chain hiccups and fluctuating grain prices taught us important lessons. While raw material price spikes occasionally push up citric acid costs, internal efficiency gains—in extraction, drying, packaging—often bring unit costs back in line. For customers, consistent supply matters every bit as much as cost. We pride ourselves on having enough buffer inventory, alternate logistics routes, and second-source packaging to keep the acid flowing even during border delays or sudden demand jumps.

    Adulteration presents a growing risk in global ingredient markets. We keep all production in-house and control ingredient transport ourselves, which makes tampering or mislabeling much less likely versus outsourced supply chains. Each batch meets traceability standards and comes with documented negative screening for yellow dextrin, foreign acids, and impurity spikes.

    Sometimes, customer challenges center on packaging—how powder flow, clumping, or oxygen ingress can slow automated filling lines or shorten shelf-life. Decades of feedback led us to test ultra-dense liners, impact-resistant bags, and tamper-evident closures, especially crucial for anhydrous batches headed to coastal or high-humidity regions. These details carry weight in maintaining batch freshness and reducing losses during storage or transit.

    Solutions and Continuous Improvement

    Continuous feedback sharpens our operations. We routinely invite customer QA teams to observe batch swabbing, in-house lab work, and packaging, building trust and identifying small improvements—whether in minimizing fines in powder grades or reducing static buildup in automated packaging. The practice of “factory floor transparency” turns audit from a box-checking exercise into real partnership. Both sides gain: customers learn our control methods, and we refine our process to broader or more demanding uses.

    Every market cycle or regulatory wave brings new technical requirements. Our team stays ahead by adding novel analytical capability—implementing high-resolution chromatography, atomic emission spectrometry, and improved water determination—to continually validate product fit. In tackling higher standards around dioxins, heavy metals, or allergen residues, we work with suppliers and authorities to push upstream improvements as well.

    For customers new to citric acid anhydrous, we default to clear onboarding—sample lots, blending trials, and ready technical support for process adjustment. In applications ranging from gel capsule manufacture to detergent powder compaction, we draw on lessons from plant floor and customer benches alike. Addressing powder flow delays, caking, or inconsistent dissolution comes from systematic engagement, not generic advice.

    The People Behind the Product

    Production expertise develops across years, not days. Our line operators, maintenance crew, laboratory analysts, and packaging staff work with responsibility because each stage can affect the next. Regular cross-training means a packaging shift can spot discrepancies first seen in drying or mixing. Internal communication and skill-building keep our citric acid batches consistent, safe, and fit for the world’s toughest applications.

    The value of citric acid anhydrous comes from more than acid strength or purity. It rests on the reliability of every shipment and the trust customers place in our plant team’s understanding of the product and process from corn starch to sealed bag. Care in handling, listening to feedback, and constant process tuning set top manufacturing apart from simple trading or brokering.

    Citric Acid Anhydrous: Trusted and Tested

    We take pride in being a manufacturer who delivers more than a commodity. Each shipment represents weeks of exacting work, every test run, and all the improvements learned over years of market and regulatory change. From bread improvers and soft drinks to medical carriers and water treatment blends, citric acid anhydrous just keeps proving its worth, batch after batch, in the toughest and most sensitive applications on the market.