Citric Acid Monohydrate
- Product Name: Citric Acid Monohydrate
- Chemical Name (IUPAC): 2-hydroxypropane-1,2,3-tricarboxylic acid monohydrate
- CAS No.: 5949-29-1
- Chemical Formula: C6H8O7·H2O
- Form/Physical State: Solid
- Factroy Site: Lingwu, Yinchuan, Ningxia, China
- Price Inquiry: sales2@liwei-chem.com
- Manufacturer: Anhui Liwei Chemical Co.,Limited
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- Citric Acid Monohydrate is a weak organic acid in crystalline form, commonly used in food and beverage processing, where precise pH control is required.
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HS Code |
904006 |
| Chemical Name | Citric Acid Monohydrate |
| Empirical Formula | C6H8O7·H2O |
| Molecular Weight | 210.14 g/mol |
| Appearance | Colorless or white crystalline powder |
| Solubility In Water | Very soluble |
| Melting Point | 30-32 °C (decomposes) |
| Ph Of 1 Percent Solution | 1.8 - 2.2 |
| Odor | Odorless |
| Taste | Strongly acidic |
| Cas Number | 5949-29-1 |
| Storage Conditions | Store in a cool, dry place |
| Stability | Stable under normal conditions |
| Uses | Food additive, preservative, acidulant, chelating agent |
| Density | 1.542 g/cm³ |
| Einecs Number | 201-069-1 |
As an accredited Citric Acid Monohydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Citric Acid Monohydrate is packaged in a 25 kg white plastic-lined kraft paper bag, labeled with product details and safety information. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL) for Citric Acid Monohydrate: Typically loads 25 metric tons, packed in 1,000 x 25 kg bags on pallets. |
| Shipping | Citric Acid Monohydrate is shipped in tightly sealed, food-grade or chemical-resistant containers to prevent moisture absorption and contamination. Packages are typically labeled in accordance with regulatory standards, handled with care to avoid spillage, and stored in cool, dry locations away from incompatible substances during transit. Standard packaging includes bags, drums, or cartons. |
| Storage | Citric Acid Monohydrate should be stored in a cool, dry, well-ventilated area away from incompatible substances, such as strong bases and oxidizers. Keep the container tightly closed and protected from moisture. Store at room temperature in a tightly sealed container. Avoid prolonged exposure to air and light, and prevent contact with metal to avoid possible corrosion. |
| Shelf Life | Citric Acid Monohydrate typically has a shelf life of 3 years when stored in a cool, dry, and well-sealed container. |
Applications of Citric Acid Monohydrate in Industrial ManufacturingAs a direct manufacturer of citric acid monohydrate, we serve a wide range of industrial sectors with a focus on process integration, regulatory adherence, and tailored composition. Below, we present the primary downstream applications where our material consistently supports production, always in line with internationally accepted industry standards and specific customer requirements. 1. Food and Beverage AcidulationFood and beverage processors use citric acid monohydrate as a pH control agent and flavor enhancer, integrated into formulations for controlled tartness, microbial stability, and shelf-life preservation. Our material features high assay consistency and meets food-grade specifications, supporting precise formulation in carbonated beverages, fruit juices, jams, dairy, and confectionery sectors. The addition step typically occurs during liquid blending or pre-mix stages to allow for proper dissolution and even acidification throughout the batch. Manufacturers adjust dosage to balance flavor, comply with local food authority limits, and minimize risk of crystallization in finished products. Downstream, our citric acid monohydrate helps ensure batch reproducibility under standard food safety and quality management systems. Industry compliance standards
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2. Pharmaceutical PreparationsPharmaceutical manufacturers rely on citric acid monohydrate for tablet effervescence, as a co-buffering agent, and for pH regulation in syrups and injectables. In solid formulations, it typically combines with sodium bicarbonate to create gas in situ, ensuring rapid disintegration and palatability enhancement. For liquid preparations, it supports API stability in aqueous environments. Compliance with compendial monographs is mandatory to ensure batch traceability and regulatory acceptance globally. Intake levels depend on final dosage form—optimization minimizes risk of tablet friability and enhances patient compliance. Material integration commonly takes place at dry-mixing, granulation, or dissolution stages depending on specific line processes. Industry compliance standards
Typical usage ratio
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3. Detergent and Cleaning Agent FormulationIndustrial and institutional detergent producers utilize citric acid monohydrate for water softening, scale removal, and pH adjustment in both powder and liquid systems. It complexes with metal ions, improving cleaning performance in hard-water environments while enhancing stability of surfactant systems. Compliance with chemical safety and consumer product regulatory frameworks is critical, particularly in markets with stringent biodegradable ingredient mandates. Dosage varies to balance chelation power, avoid residue formation, and ensure compatibility with other actives. Our material is introduced during primary batching before carbonation or optionally as a post-mix to fine-tune final formulation pH on modern automated lines. Industry compliance standards
Typical usage ratio
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4. Industrial Water Treatment and Boiler Scale InhibitionManufacturers of water treatment solutions apply citric acid monohydrate for system descaling, corrosion control, and ion exchange resin bed regeneration. Its capacity to dissolve mineral deposits makes it indispensable for preventive maintenance of closed and open-loop heating, cooling, and processing lines. Regulatory compliance ensures safe discharge practices and operator safety during application. Treatment engineers regulate concentration based on water chemistry analysis, targeting specific scale compositions, flow rates, and exposure times. Citric acid monohydrate enters water treatment systems as a batch chemical or via timed metering pumps, supporting maintenance protocols for power plants, food production facilities, and HVAC systems. Industry compliance standards
Typical usage ratio
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5. Cosmetics and Personal Care FormulationsPersonal care formulators incorporate citric acid monohydrate for pH adjustment and mild chelation in a wide variety of cosmetic products including hair care, skin care, and oral hygiene lines. It maintains desired acidity for product stability and consumer safety, reduces oxidative degradation of sensitive actives, and improves rinse-off profiles in shampoos and body washes. Cosmetic regulatory requirements emphasize ingredient traceability and microbiological safety. Formulators adjust levels based on target final pH and interaction with other frame ingredients. Our material enters the production line during the aqueous phase preparation before emulsification or surfactant addition, ensuring reliable pH establishment prior to batching for filling. Industry compliance standards
Typical usage ratio
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6. Metal Surface Treatment and PicklingCitric acid monohydrate is a primary component for metal cleaning and passivation, employed by fabricators, stainless steel processors, and parts manufacturers. It removes rust, oxides, and light scale from ferrous and non-ferrous metals in immersion or circulation cleaning systems, with safe handling and minimal fume production compared to mineral acid alternatives. Compliance with metalworking safety, discharge, and effluent standards is mandatory on manufacturing sites. Addition rates depend on degree of soiling and surface area. Operators dissolve the material in hot or ambient water to prepare pickling solutions, continuously monitor concentration during treatment, and neutralize rinsate before disposal. Industry compliance standards
Typical usage ratio
Downstream process integration
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Competitive Citric Acid Monohydrate prices that fit your budget—flexible terms and customized quotes for every order.
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Tel: +8615380400285
Email: sales2@liwei-chem.com
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- Citric Acid Monohydrate is manufactured under an ISO 9001 quality system and complies with relevant regulatory requirements.
- COA, SDS/MSDS, and related certificates are available upon request. For certificate requests or inquiries, contact: sales2@liwei-chem.com.
Citric Acid Monohydrate: Behind the Factory Gates
In our plant, the production of citric acid monohydrate never pauses. Demand spans several industries and every day we receive calls about product differences and the reasons for choosing this model over other food acids or citric acid forms. If you’ve ever wondered why our teams treat every batch of citric acid monohydrate with such care, the reasons start on the shop floor.
How Citric Acid Monohydrate Comes to Life in Our Factory
We’ve built our reputation on consistent quality. Citric acid monohydrate leaves the reactors here in free-flowing white crystalline powder form. Each particle shines with over 99.5% purity—something only possible because our purification process leaves little room for error. You can see the results in a simple glance at the daily moisture readings. Uniformity matters because every client, from beverage producers to pharmaceutical formulators, relies on the acid’s steady composition. If you open a bag in our warehouse, the product always delivers the same dusting of fine crystalline powder that signals accurate hydration levels and purity.
Water content means more than customers realize. Citric acid monohydrate carries a single molecule of water for every citric acid molecule. This trait sets it apart from the anhydrous version, which holds no water. While both forms appear similar, their behavior in processing lines or final products can differ. With monohydrate, storability and weighing come easier: powders resist clumping from low ambient moisture. That one step—from fermentation broth to precise drying and crystallization—gives factories like ours a batch with stable handling qualities. There’s no fight with sticky granules spilled on the conveyor belt, and as odd as it sounds, those small practicalities keep production humming.
Why Food, Pharma, and Industry Prefer Citric Acid Monohydrate
Beverage makers prefer this product for its solubility. Once the powder hits water or a syrup tank, it dissolves cleanly and quickly. No surprise chunks swim in the liquid, and there’s none of that stubborn grit you might experience with some organic acids. Years ago, one client switched to citric acid monohydrate, saying, “You saved us hours of cleanup and blending headaches.” The experience isn’t unique. In jams, jellies, canned fruits, and soft drinks, this acid gives a sharp, pleasant tang and controls pH as recipes demand. For jam and fruit packers, a quick pH drop from citric acid monohydrate means fewer problems with spoilage before the lid goes on. Batch after batch, exacting standards on sourness need batches that dissolve the same way, every time. No surprises, just a reliable kick of tartness and preservation power.
In the pharmaceutical wing, every batch we ship finds use controlling acidity or balancing formulas in syrups, antacids, and effervescent tablets. Unlike some acidulants, citric acid monohydrate’s traceability and test data meets international pharmacopoeias. Years back, a customer in the supplement market told us, “If our testing machine finds even the slightest deviation, it triggers a recall risk.” We’ve built our operations to avoid that scenario. Every raw material input, fermentation run, and drying cycle links back to documentation. This helps pharma clients pass audits and gives us confidence in our systems.
We also ship to cleaning product makers. They come to us because this acid chelates metal ions, dissolving hard water scale and rust. Citric acid monohydrate shows up in dishwasher tabs, all-purpose sprays, and even coffee machine descalers. In these industries, consistency means the difference between a smooth batch run and an hour scraping clogged mixing nozzles. Clients have tested competitor samples against ours, only to find that proper moisture management avoids caking during packaging—even for months on warehouse shelves.
Quality Control Weighs In
Having walked the line between production, packaging, and dispatch, I can tell you no improvement stands alone. Our operators test each batch for purity using titration and HPLC. They check that iron, lead, and other impurities never stray above strict food and pharma limits. Some days, we reject batches that most would call perfectly usable; a tiny yellow tinge or a spec of dust in an otherwise clear sample sets off alarms. A supervisor once pointed out, “Your last percent of effort in quality control is the hardest to achieve, but it’s where reliability gets built.” Auditors drop in unexpectedly, run their own panels, and challenge our readings. Passing those tests isn’t just about certificates—it’s about trust with end-users who may never know our name but depend on the product’s quiet performance.
Moisture content gets special attention. Our product leaves the dryer at around 8-9% water by weight—much higher than the anhydrous type. This range might sound trivial until you face the actual milling, packaging, and downstream processing steps. If moisture creeps up too high, the product clumps. Too low, it becomes dusty, tough to handle, and loses flow. Over the years, we’ve tuned our dryers and dehumidifiers using hundreds of samples, batch after batch, to find the sweet spot. Each change in weather, shift duration or raw material can affect outcomes, but our control systems catch changes early to stop them causing problems in final packing.
Comparing with Anhydrous and Other Acids
Our customers often ask why they shouldn’t just use anhydrous citric acid. It’s a fair question, since both versions acidify foods and dissolve in water. The trick lies in their different moisture content. Anhydrous citric acid contains almost no water. This gives it a firmer, less hygroscopic character, which some candy makers and powder blenders need. But this brittle quality also means more dust—troublesome in automated lines, and rough on air filters and mixing staff. Citric acid monohydrate, in contrast, brings just enough water to aid flow, weigh out accurately in humid climates, and resist static cling. Industries needing strictly water-free ingredients for sensitive blends may favor anhydrous, but the vast majority of customers choose our monohydrate model. Their factories run quieter, packaging lines see less maintenance, and final products keep to specification without an extra step.
We’ve tried to help customers troubleshoot misapplications, too. In industrial water treatment, clients sometimes swap monohydrate for anhydrous. At first, nothing looks amiss—but months later, weighing errors or caking in silos back up operations. Education helps here. Our teams visit sites to explain, batch weigh the real-world moisture contents, and walk operators through correct storage advice. Most users come around to the monohydrate version once they factor in ease of handling and consistent metering.
Some industries, like chelation for detergents, don’t see much impact from switching between monohydrate and anhydrous, so long as dosage gets adjusted for the difference in water content. Bakers or oil processors, though, sometimes need the slow-release acidification that only monohydrate gives, especially in controlled leavening processes. Small tweaks in manufacturing, like swapping out one acid for another or switching from granular to fine powder, can upset the careful balance that keeps products stable on store shelves. This explains why we spend so much time running side-by-side trials and sharing batch data openly with partners—change without data brings trouble.
Ensuring Food Safety and Traceability
Traceability stands as a pillar in this business. We track every delivery back to its manufacturing date and batch number. In industries with zero tolerance for error, such as infant formula or injectables, our detailed logs and sample retention policy matter more than any claim on a label. Our logs can retrace any carton of powder back through raw material intake, fermentation batch, filtration runs, and packing shifts. Risk management extends to allergen controls and cross-contamination checks; though citric acid’s origins lie in fermentation, not citrus fruit harvest, the facility still segregates every input and checks air systems to prevent dust drift. Auditors arrive with lists of food defense questions, and we walk them through every contamination safeguard, from water sourcing to employee hygiene.
Customers from overseas sometimes worry about country of origin or process details—especially in the wake of media stories about tainted ingredients. We respond with lab certificates, video walk-throughs, and batch-specific data. Our role as a direct manufacturer brings accountability, not just paperwork. We don’t hide behind brokers or faceless resellers. If a customer discovers an issue, they speak straight to our quality department, not a help desk. One day, a bakery partner flagged appearance changes in their glaze. We pulled records, ran parallel tests, and traced the problem to a switch in their own process—our batch had stayed well within spec. By opening up our records and methods, we turned a potential argument into a learning session for both sides.
The Environmental Angle
Chemical manufacturing faces hard scrutiny about environmental consequences. Citric acid, especially as a fermentation product, offers a gentler profile compared to legacy chemical acidulants. In our plant, sugar-rich feedstock (often from starchy crops like corn or cassava) drives fermentation tanks. The yield from this process turns what used to be agricultural by-product into something of value. Instead of harsh mineral acids, biological synthesis requires lower temperatures and less hazardous side-products. Of course, any factory can lose sight of best practices if growth outpaces environmental management. We’ve adapted our wastewater systems, capturing spent biomass for fertilizer use. This circular approach not only reduces waste but creates new revenue channels for farms. Every tonne of citric acid monohydrate carries an environmental story—how effectively we use energy, recycle, and minimize landfill.
Packaging creates another challenge. Years ago, most citric acid shipped in plain woven sacks or drums. Moisture uptake or accidental damage risked whole batches. Now, with multilayer plastic liners and improved sealants, bags protect against ambient humidity and extend shelf life. Bulk buyers opt for FIBCs with built-in liners, cutting both waste and labor costs on arrival. Still, each improvement comes with tradeoffs. Plastic creates disposal questions; we source recyclable liners and invest in lightweighting bags where possible. These small choices help customers save on transport and reduce environmental impact down the line.
Why Direct Manufacturing Matters
Our roots as manufacturers give us a different perspective than contract packers or Purely trading houses. Factory workers, engineers, chemists, and logistics teams have skin in the game. If process or material happens to fail, downtime falls on us and our customers—not a distant supplier halfway across the globe. This direct chain allows for quick changes to models or specs. Last year, a jam manufacturer needed a specific particle size cut to avoid undissolved specks in clear fillings. Instead of relaying messages through agents, we shifted our crystallization process and delivered the new variant within weeks. As manufacturing complexity grows, this close feedback loop translates to better products and truly responsive service.
Sometimes, new entrants ask if investing in citric acid monohydrate over other acidulants pays off. From decades of experience, the answer remains yes in most mainstream food and pharma lines. You can see how the acidity builds gently in a beverage blend or how the pH shifts reliably in a tablet mixer. Everyone benefits—line managers, quality control staff, and even the workers filling sacks at the end of the packing hall. This reliability didn’t happen overnight; it arose from careful adaptation, routine feedback, and hundreds of partnerships with those who never see our factory floors but trust our name on the bag or drum.
Challenges and Innovations Ahead
Every manufacturing journey faces hurdles. Energy costs, shifts in raw material supply, tightening purity specifications, and customer demands for ever-finer powders or novel packaging keep us busy. Our teams adapt by trialing greener energy sources, partnering with local suppliers, and automating sampling and monitoring systems. Global trade volatility can spike costs, but direct manufacturing allows us to buy in bulk and pass savings on to stable clients.
One persistent challenge is the wider public’s occasional confusion about citric acid’s origin. Because we produce it using fermentation—not fruit extraction—questions about allergenic potential or ‘natural’ status pop up often. Full disclosures, open tours, and near-daily dialogues with regulatory officials help clear misconceptions. “Will this citric acid affect citrus-allergic consumers?” comes up nearly monthly. The answer draws on decades of lab and market experience: the acid contains no proteins from fruit, offering a clear safety margin for supply chains requiring hypoallergenic inputs.
Looking ahead, our focus on refining the process continues. Particle size customization, improved energy management, and pushing minor impurity levels ever lower make up our research roadmap. By listening to end users—food scientists, homecare formulators, pharmacists—we find pain points that don’t always appear in specification sheets but matter just as much on the production floor. This feedback turns up issues like powder flow in pick-and-place lines, compatibility with other minor ingredients, or unexpected behavior under heavy mixing. Factory-side conversations spring new solutions that trading desks cannot imagine or execute.
Citric Acid Monohydrate’s Real Value
Citric acid monohydrate, crafted with steady hands and a relentless pursuit of detail, forms the backbone of countless safe, flavorful, and stable products. Our job doesn’t end at the gates. Each shipment sends a piece of our process know-how and trust into a larger world of finished goods. Having lived through every audit, batch review, and customer troubleshooting call, we know exactly why reliable citric acid monohydrate earns its place—batch after batch, product after product. It’s made not from abstract standards, but practical demands, patient improvements, and the pride of a skilled team working behind the scenes.
